Как Вы исполняете роль Пользователя Active Directory в Powershell?

В Вашем приложении ASP.NET необходимо будет явиться олицетворением действительной AD учетной записи с корректными полномочиями:

http://support.microsoft.com/kb/306158

Вот класс, который я использую для исполнения роли пользователя.

using System;
using System.Data;
using System.Configuration;
using System.Web;
using System.Web.Security;
using System.Web.UI;
using System.Web.UI.WebControls;
using System.Web.UI.WebControls.WebParts;
using System.Web.UI.HtmlControls;

namespace orr.Tools
{

    #region Using directives.
    using System.Security.Principal;
    using System.Runtime.InteropServices;
    using System.ComponentModel;
    #endregion

    /// <summary>
    /// Impersonation of a user. Allows to execute code under another
    /// user context.
    /// Please note that the account that instantiates the Impersonator class
    /// needs to have the 'Act as part of operating system' privilege set.
    /// </summary>
    /// <remarks>   
    /// This class is based on the information in the Microsoft knowledge base
    /// article http://support.microsoft.com/default.aspx?scid=kb;en-us;Q306158
    /// 
    /// Encapsulate an instance into a using-directive like e.g.:
    /// 
    ///     ...
    ///     using ( new Impersonator( "myUsername", "myDomainname", "myPassword" ) )
    ///     {
    ///         ...
    ///         [code that executes under the new context]
    ///         ...
    ///     }
    ///     ...
    /// 
    /// Please contact the author Uwe Keim (mailto:uwe.keim@zeta-software.de)
    /// for questions regarding this class.
    /// </remarks>
    public class Impersonator :
        IDisposable
    {
        #region Public methods.
        /// <summary>
        /// Constructor. Starts the impersonation with the given credentials.
        /// Please note that the account that instantiates the Impersonator class
        /// needs to have the 'Act as part of operating system' privilege set.
        /// </summary>
        /// <param name="userName">The name of the user to act as.</param>
        /// <param name="domainName">The domain name of the user to act as.</param>
        /// <param name="password">The password of the user to act as.</param>
        public Impersonator(
            string userName,
            string domainName,
            string password)
        {
            ImpersonateValidUser(userName, domainName, password);
        }

        // ------------------------------------------------------------------
        #endregion

        #region IDisposable member.

        public void Dispose()
        {
            UndoImpersonation();
        }

        // ------------------------------------------------------------------
        #endregion

        #region P/Invoke.

        [DllImport("advapi32.dll", SetLastError = true)]
        private static extern int LogonUser(
            string lpszUserName,
            string lpszDomain,
            string lpszPassword,
            int dwLogonType,
            int dwLogonProvider,
            ref IntPtr phToken);

        [DllImport("advapi32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        private static extern int DuplicateToken(
            IntPtr hToken,
            int impersonationLevel,
            ref IntPtr hNewToken);

        [DllImport("advapi32.dll", CharSet = CharSet.Auto, SetLastError = true)]
        private static extern bool RevertToSelf();

        [DllImport("kernel32.dll", CharSet = CharSet.Auto)]
        private static extern bool CloseHandle(
            IntPtr handle);

        private const int LOGON32_LOGON_INTERACTIVE = 2;
        private const int LOGON32_PROVIDER_DEFAULT = 0;

        // ------------------------------------------------------------------
        #endregion

        #region Private member.
        // ------------------------------------------------------------------

        /// <summary>
        /// Does the actual impersonation.
        /// </summary>
        /// <param name="userName">The name of the user to act as.</param>
        /// <param name="domainName">The domain name of the user to act as.</param>
        /// <param name="password">The password of the user to act as.</param>
        private void ImpersonateValidUser(
            string userName,
            string domain,
            string password)
        {
            WindowsIdentity tempWindowsIdentity = null;
            IntPtr token = IntPtr.Zero;
            IntPtr tokenDuplicate = IntPtr.Zero;

            try
            {
                if (RevertToSelf())
                {
                    if (LogonUser(
                        userName,
                        domain,
                        password,
                        LOGON32_LOGON_INTERACTIVE,
                        LOGON32_PROVIDER_DEFAULT,
                        ref token) != 0)
                    {
                        if (DuplicateToken(token, 2, ref tokenDuplicate) != 0)
                        {
                            tempWindowsIdentity = new WindowsIdentity(tokenDuplicate);
                            impersonationContext = tempWindowsIdentity.Impersonate();
                        }
                        else
                        {
                            throw new Win32Exception(Marshal.GetLastWin32Error());
                        }
                    }
                    else
                    {
                        throw new Win32Exception(Marshal.GetLastWin32Error());
                    }
                }
                else
                {
                    throw new Win32Exception(Marshal.GetLastWin32Error());
                }
            }
            finally
            {
                if (token != IntPtr.Zero)
                {
                    CloseHandle(token);
                }
                if (tokenDuplicate != IntPtr.Zero)
                {
                    CloseHandle(tokenDuplicate);
                }
            }
        }

        /// <summary>
        /// Reverts the impersonation.
        /// </summary>
        private void UndoImpersonation()
        {
            if (impersonationContext != null)
            {
                impersonationContext.Undo();
            }
        }

        private WindowsImpersonationContext impersonationContext = null;

        // ------------------------------------------------------------------
        #endregion
    }
}

Эта статья о блогах MSDN, кажется, показывает способ сделать это, я не смог попробовать его все же, но сообщу, когда я делаю.

http://blogs.msdn.com/webdav_101/archive/2008/09/25/howto-calling-exchange-powershell-from-an-impersonated-thead.aspx

You might need a patch.

From: http://support.microsoft.com/kb/943937

An application cannot impersonate a user and then run Windows PowerShell commands in an Exchange Server 2007 environment

To resolve this problem, install Update Rollup 1 for Exchange Server 2007 Service Pack 1.