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HttpClient-4.5, Use TLSv1.2, вы должны закодировать следующим образом:

 //Set the https use TLSv1.2
private static Registry<ConnectionSocketFactory> getRegistry() throws KeyManagementException, NoSuchAlgorithmException {
    SSLContext sslContext = SSLContexts.custom().build();
    SSLConnectionSocketFactory sslConnectionSocketFactory = new SSLConnectionSocketFactory(sslContext,
            new String[]{"TLSv1.2"}, null, SSLConnectionSocketFactory.getDefaultHostnameVerifier());
    return RegistryBuilder.<ConnectionSocketFactory>create()
            .register("http", PlainConnectionSocketFactory.getSocketFactory())
            .register("https", sslConnectionSocketFactory)
            .build();
}

public static void main(String... args) {
    try {
        //Set the https use TLSv1.2
        PoolingHttpClientConnectionManager clientConnectionManager = new PoolingHttpClientConnectionManager(getRegistry());
        clientConnectionManager.setMaxTotal(100);
        clientConnectionManager.setDefaultMaxPerRoute(20);
        HttpClient client = HttpClients.custom().setConnectionManager(clientConnectionManager).build();
        //Then you can do : client.execute(HttpGet or HttpPost);
    } catch (KeyManagementException | NoSuchAlgorithmException e) {
        e.printStackTrace();
    }
}